I am reading about the extraordinary math and science contributions of John von Neumann in Ananyo Bhattacharya’s book The Man from the Future. I definitely get the feeling that von Neumann was indeed a rare genius. I also got the feeling that maybe I should have persevered in learning more math when I was younger. If so, not only would I have a better appreciation of von Neumann’s achievements, I would also be able to tackle some interesting problems in my research that require mathematically modeling beyond my current abilities. Feynman’s quote notwithstanding, I would like to better understand quantum mechanics since I use it heavily in my research.
Today’s blog post is about Chapter 3 of Bhattacharya’s engaging book. The chapter is titled “The Quantum Evangelist” and leverages the author’s physics background. While I know a number of facts about the history of the development of quantum mechanics, I learned a lot more about von Neumann’s contributions and the context surrounding his work. Reading this chapter gave me a better idea of the conceptual differences between Heisenberg’s matrix mechanics and Schrodinger’s wave mechanics. The connections to set theory in mathematics (and Hilbert’s program of systematization) helped clarify the context. Quoting the author: “An atom has an infinite number of orbits… so Heisenberg’s matrices must also be of infinite size to represent all possible transitions between them. The members of such a matrix can… be lined up with a list of the counting numbers – they are ‘countably’ infinite. Schrodinger’s formulation, on the other hand, yielded wave functions describing… an uncountably infinite number of possibilities. An electron that is not bound to an atom… could be literally anywhere.”
I now have a better appreciation of Dirac’s “ingenious trick to merge the ‘discrete’ space of Heisenberg’s matrices and the ‘continuous’ space of Schrodinger’s waves” with the delta function. Bhattacharya describes it as a “salami slicer, cutting up the wavefunction into ultra-thin slivers in space”. While Hilbert space still feels fuzzy to me and I don’t quite comprehend it, I can dimly see where square-integrable functions come from. When I teach quantum chemistry, I tell students about this important property and its practical uses along with Born’s probability postulate, I had never talked about their mathematical basis (because I didn’t understand it myself).
Where does von Neumann come into the story? Given his mathematical talents, he realized that square integrable functions “can be represented by an infinite series of orthogonal functions, sets of mathematical independent functions that can be added together to make any other… How much of each function is required is indicated by their coefficients... [which] were exactly the elements that appear in the state matrix.” In my class, I invoke orthogonality from a consequence of Hermitian operators. I discuss the importance of having linearly independent functions and spaces (e.g. Cartesian space or polar coordinates) conceptually but my students still struggle to think about it. Linear algebra is not a pre-requisite for my class and most students haven’t taken it. Neither have I for that matter. Until reading this chapter, I had not realized the connection between square integrable wavefunctions and orthogonality. In my class, when we get to multi-electron multi-atom systems, I introduce students to manipulating linear combinations of functions that sum up (invoking the principle of superposition) to get better results when solving the Schrodinger equation. They learn that the sum of the squares of the coefficients must add up to one, but I hadn’t made the connection to square-integrability.
There is plenty more in the chapter about the weirder aspects of quantum mechanics, wavefunction collapse, hidden variable theory, pilot waves, Bell inequalities, and Many Worlds. But what really stood out to me was where square integrable functions come from (as part of Hilbert space) and how they connected to orthogonal component wavefunctions. All these connections were a revelation to me, and I’d been teaching for a quarter of a century! How little I know. How much more to learn. This reminds me that I should get back to Beyond Weird by Philip Ball.