Last week we discussed precipitation reactions in my General
Chemistry class. I tried to impress upon the students how surprising it would
seem to someone observing such a chemical reaction for the first time. Mix two
clear and colorless solutions together, i.e., two substances that look just
like liquid water, and out pops a solid! Most of the solids are white in
standard demos (and perhaps the jaded student does not find this all that
interesting) but lead iodide (PbI2) is yellow. I wonder if an early
alchemist observing a similar reaction might have wondered if this was a route
to making gold. I’m not sure my students were all that impressed (having seen
this reactions in lab the week before). They might even have found writing out
the chemical equations tedious. At the very least I might have amused them with
my opening Power Point slide shown below as they were filing into class. Lame,
but it still elicits chuckles.
Let’s stop to think about this for a moment. We often see
solids dissolve in water (salt and sugar for example) but in everyday
experience we rarely encounter solids appearing where you only had liquids to
begin with. It’s almost magical. If you had a chemistry set as a kid, you might
have had the magical experience of making your own precipitate or growing
crystals. Think about the child-like wonder in seeing something surprising that
might not have conformed to your everyday experience! (In the age of the iPad
with fancy addictive games, it’s unclear to me if today’s kids will find it
fascinating.) I’m pretty sure the alchemists did – especially since they did
not know the underlying chemistry. I wonder if part of why the students are
jaded is because the explanation seems so mundane and straightforward. (Maybe I
need to spice it up!) Knowledge should be exciting, not boring!
What questions did students have on this unit? The first one,
predictably, was “Do we have to memorize the solubility rules?” This was the
final thing we talked about in class where my emphasis was not on memorizing
but in trying to draw general principles from the rules – really a list of
observational facts. That’s how you put together a theory! (Or perhaps a
working hypothesis that can be tested!) But more on that in a later post since
I’ve been thinking about philosophy of science and the makings of a scientific
theory. In any case, I hope the students understood the idea of how to
formulate such a theory based on what they had learned earlier in the semester.
We had discussed lattice energies of ionic compounds, packing in solid
crystalline structures, and dynamic equilibrium. I waved my hands and drew
pictures on the board as I drew students into the discussion. I was at least
interesting enough that they were paying attention instead of watching the
clock (because we ran over by 2 minutes and they didn’t notice). I suppose I
could have an assessment question to check if they really did “get it”.
A related phenomena that I think the alchemists would find
particularly interesting is sublimation. Some solid substances will turn
directly into gases (skipping the liquid state) upon heating. Dry ice (solid
carbon dioxide) is an example familiar to most people. We also covered this in
class but I neglected to make the connection to alchemy and teleportation!
(More on the latter in a moment.) Iodine works well in a demo because of the
lovely purple hue as it sublimes. I did not do the demo this year in my lecture
class (noxious fumes) but I have done so when I teach lab (with the apparatus in a fume hood). If you put a watch glass
over beaker so you can see the crystals reforming on the base
of the watch glass. (Putting a small piece of ice on the watch glass hastens
the deposition.) Other substances exhibiting this behavior include arsenic,
camphor and ammonium chloride (sal ammoniac). Arsenic and sal ammoniac would
have been familiar ingredients to the medieval alchemist, and camphor was available
to Europe as a spice through the Arab traders.
Why might sublimation and deposition be of particular
significance to the alchemist or magician? I think the process is akin to
teleportation! A solid substance disappears into vapors, only to be reformed
somewhere else. In the TV series Once Upon A Time, when the evil queen
teleports she is engulfed by a swirling purple smoke that resembles the color
of iodine vapor! (I wonder if that’s where they got the idea.) Furthermore,
sublimation could also be used as a tool for purification, much like
distillation – a process core to alchemist’s work. Since alchemy was often
infused with the religious symbol of Christianity, one might see the analogy a
soul rising upward (or heavenward). If my students lived in the medieval world
and witnessed such alchemy, they might think it sublime!