My introductory chemistry courses begin with the following
question: “What is matter and why does it matter?” We consider several
ideas from the ancient Greek philosophers, before a final compare-and-contrast of
Democritus’ Atomic theory and the Four Element system championed by Aristotle.
Is matter fundamentally made up of atoms – discrete indivisible particles too
small to observe? Or is matter a continuous blend of principles – embodied by
the ‘elements’ earth, water, air, fire? In the alchemists' view, matter can be transmuted – you could turn lead into gold
with the right ingredients in the right proportions.
We then jump almost two thousand years to Dalton’s
Atomic theory, and define terms that are used in modern chemistry:
element, atom, molecule, compound. The periodic table is introduced and
elements are distinguished by their number of protons. Since the protons reside
in a tiny nucleus not subject to chemical reactions (which involve only the
movement of electrons on the atoms periphery), transmutation is very difficult
unless very high energies are involved that allow nuclear reactions to take
place. We do discuss spontaneous transmutation via radioactive decay.
Once the basics of how electrons arrange themselves
in atoms is established, we can start discussing chemical properties of
elements and how they are arranged in the periodic table. The history of how the periodic table came to be has many twists and turns. Among several
early attempts at formulating periodic law that I discuss briefly in class, one
that throws the students for a loop (pun intended) is Hinrichs’ spiral. However, I had never delved further into his other ideas until reading about
Hinrichs in The Lost Elements.
Apparently in the mid-1850s, Hinrichs developed a
theory of prime matter based on a universal element he called pantogen. According to Hinrichs, what we
call chemical elements are simply different combinations of pantogen. In his
scheme, pantogen had a relative atomic weight of 1/128 compared to hydrogen. In
a nod to Lavoisier, he utilized precision measurements of experimental
relative atomic weights to make his case: “…if, from a liter of pantogen
weighing 0.697 mg, one were to subtract the observed experimental weights of 1
liter of O, H, N, and C (gases), the new atomic weights of these elements would
turn out to be the whole numbers 16, 1, 14, and 12, respectively.” (These are
the atomic numbers of those four elements.)
One thing I try and emphasize in introductory
chemistry is the strangeness of our model of the atom. Hydrogen, the simplest
atom, has a positively charged proton that’s tiny in size, yet 1840 times more
massive than the negatively charged electron that roams around in mostly empty
space – like a bee in a cathedral. That’s actually a very counter-intuitive
idea. Hinrichs thought that hydrogen is made up of 128 atoms of
pantogen. He didn’t know about protons and electrons. However, his idea isn’t
too far-fetched given that after protons and electrons were discovered, there
was a proposal that the hydrogen nucleus was actually made up of approximately
1840 ‘plus-trons’ and 1839 electrons; a single electron happened to have
escaped from the nucleus. (I named these hypothetical particles ‘plus-trons’ so
as not to confuse them with positrons.)
The pantogen scheme did not catch on, apparently
because very few people actually read Hinrichs’ work. You, dear reader, have
probably never heard of pantogen. Apparently very few people read the work of
Nikolai Morozov either, because otherwise our subatomic elements might be
anodium, cathodium, and archonium – instead of the proton, electron, and
neutron. A Google search on any of these terms gives you results unrelated to
the theory of matter. I suppose they no longer matter.
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